The couple who raise Maddox, 11, Pax, 8, Zahara, 7, Shiloh, 6, and 4-year-old twins Knox and Vivienne, went to a tiny post office in Littlebourne village, Kent, here.
The family behaved very normally with Jolie keeping all children under control.
"It was so cute. All the children sent messages to Father Christmas and were absolutely beautifully behaved. Just like any other kids in a sweet shop they were excited, but Angelina controlled them perfectly. She was so polite and a really nice person," thesun.co.uk quoted Fiona Lindsay, post office assistant as saying.
The staff were surprised to see Hollywood stars in their stores but gradually became comfortable with their presence.
“I was quite shocked at first but Angelina was so lovely I soon relaxed. The children bought a packet of sweets each, plus a few toys and some magazines, and we ended up having a general chat about how they all were and what they were going to eat that night," Lindsay said.